Synthesis and structure-property comparisons of hydrogenated poly(oxanorbornene-imide)s and poly(norbornene-imide)s prepared by ring-opening metathesis polymerization
نویسندگان
چکیده
منابع مشابه
Polyterpenes by ring opening metathesis polymerization of caryophyllene and humulene
Polymers with their myriad functions are indispensable to any modern technology. Today, their production is largely based on fossil fuels. In view of their limited range, other sources are desirable on the long term. Beyond such considerations, renewable resources are also attractive as they can contain unique chemical structures. Thus, carbohydrates, fatty acids or terpenes contain a wealth of...
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Alcohol is the answer! An inactive, air-stable, dimeric molybdenum alkylidyne complex is activated toward ring-opening alkyne metathesis polymerization (ROAMP) by the addition of methanol. The ROAMP is compatible with water and phenol-containing substrates and with the in situ photochemical generation of alkyne monomers from cyclopropenones.
متن کاملCatalytic living ring-opening metathesis polymerization.
In living ring-opening metathesis polymerization (ROMP), a transition-metal-carbene complex polymerizes ring-strained olefins with very good control of the molecular weight of the resulting polymers. Because one molecule of the initiator is required for each polymer chain, however, this type of polymerization is expensive for widespread use. We have now designed a chain-transfer agent (CTA) cap...
متن کاملSupported Catalysts Useful in Ring-Closing Metathesis, Cross Metathesis, and Ring-Opening Metathesis Polymerization
Ruthenium and molybdenum catalysts are widely used in synthesis of both small molecules and macromolecules. While major developments have led to new increasingly active catalysts that have high functional group compatibility and stereoselectivity, catalyst/product separation, catalyst recycling, and/or catalyst residue/product separation remain an issue in some applications of these catalysts. ...
متن کاملVoltage-assisted capillary LC of peptides using monolithic capillary columns prepared by ring-opening metathesis polymerization.
We examined the use of monolithic capillary columns prepared via ring-opening metathesis polymerization (ROMP) for peptide separation in voltage-assisted capillary LC (voltage-assisted CLC). In order to demonstrate their potential for peptide separation, ROMP-derived monoliths with RP properties were prepared. The preparation procedure of monoliths was transferred from ROMP monoliths optimized ...
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ژورنال
عنوان ژورنال: Journal of Polymer Science Part A: Polymer Chemistry
سال: 2012
ISSN: 0887-624X
DOI: 10.1002/pola.26171